Quantum tunneling of two coupled single-molecular magnets

نویسندگان

  • Jian-Ming Hu
  • Zhi-De Chen
چکیده

Two single-molecule magnets are coupled antiferromagnetically to form a supramolecule dimer. We study the coupling effect and tunneling process by means of the numerical exact diagonalization method, and apply them to the recently synthesized supramoleculer dimer [Mn4]2. The model parameters are calculated for the dimer based on the tunneling process. The absence of tunneling at zero field and sweeping rate effect on the step height in the hysterisis loops are understood very well in this theory.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Modeling and Simulation of a Molecular Single-Electron Transistor

In this paper, to understand the concept of coupling, molecule density of states that coupled to the metal electrodes will be explained then, based on this concept, a weak and strong coupling for the molecules attached to the metal electrodes will be described. Capacitance model is used to explore the connection of addition energy with the Electron affinity and the ionization energy of the mole...

متن کامل

A Brief Introduction to Single Molecular Magnets

Single Molecular Magnets(SMM), has attracted much interest. Their large spin and quantum behavior at a mesoscopic scale, indicates rich physics behind these unusual phenomena as well as prospective application values. In this article, quantum tunneling magnetization (QTM), the origin of the magnetism in SMM, is discussed. Then it is followed by two typical cases: integer spin SMM and 1/2 spin SMM.

متن کامل

Transverse magnetization and transient oscillations in the quantum tunneling of molecular magnets

We calculate the response of a molecular magnet subject to a time-varying magnetic field and coupled to a heat bath. We propose that observations of calculated oscillations transverse to the field direction may be an effective way of demonstrating quantum tunneling and thus probing the details of level repulsion. The effective model of a triangle of Heisenberg spins and weak anisotropies, as ha...

متن کامل

Quantum Tunneling of the Magnetization in the Ising Chain Compound Ca3Co2O6

The magnetic behavior of the Ca3Co2O6 spin chain compound is characterized by a large Ising-like character of its ferromagnetic chains, set on triangular lattice, that are antiferromagnetically coupled. At low temperature, T < 7K, the 3D antiferromagnetic state evolves towards a spin frozen state. In this temperature range, magnetic field driven magnetization of single crystals (H//chains) exhi...

متن کامل

Resonant and Kondo tunneling through molecular magnets

Transport through molecular magnets is studied in the regime of strong coupling to the leads. We consider a resonant-tunneling model where the electron spin in a quantum dot or molecule is coupled to an additional local, anisotropic spin via exchange interaction. The two opposite regimes dominated by resonant tunneling and by Kondo transport, respectively, are considered. In the resonant-tunnel...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2003